Preparation of biodiesel from waste cooking oil pdf

Abstractbiodiesel production from waste cooking oil was obtained using thermomyces lanuginosus tl lipase e. Biodiesel from waste cooking oil, obtained through the use of our immobilized lipase, after 24 h of synthesis, presents a linolenic methyl ester amount equal to 0. Oilseed plants are used for the production of biodiesel through the process called transesterification reaction which is a process by which alcohol reacts with vegetable oil in the presence of. Alternate fuels should be economically attractive in order to compete with currently used fossil fuels. Acidcatalyzed preparation of biodiesel from waste vegetable oil. Water impedes the biodiesel reaction resulting in only partial conversion of the oil to biodiesel. Waste cooking oil was obtained from our college mess and utilized to prepare biodiesel. Biodiesel may be used in any diesel automotive engine in its pure form or blended with petroleumbased diesel. In the research presented herein, snail shell waste was used as catalyst for the production of the biodiesel process. Preparation of biodiesel from waste cooking oil via twostep catalyzed process. The process of biodiesel made from waste cooking oil via acid catalyst was studied in order to eliminate the waste cooking oil pollution and realize the health of waste oil use. F over an electric burner to make the oil easier to pour for filtration.

Ethyl alcohol with sodium hydroxide as a catalyst was. However, the commercialization of biodiesel is difficult because of the use of highpriced vegetable oil in the manufacturing of biodiesel. Biodiesel produced from this method has a higher cost compared to fossil fuels. It is prepared from waste vegetable oils and animal fats by transesterification process. In the present study, the transesterification of soybean oil into. Pdf biodiesel production from waste cooking oil researchgate. Preparation of biodiesel from waste cooking oil via twostep. Whereas waste oils which have not any treatment first, will pollute the environment. Optimized biodiesel production from waste cooking oil wco. To minimize the biofuel cost, in recent days waste cooking oil was used as feedstock. As this method becomes increasingly popular, accumulation of. In todays world, oilfrying method is widely used due to the contribution of good taste, attractive colour and better presentation of the food. In this research, waste cooking oil is used as raw material with potassium hydroxide.

But the main problem of using waste cooking oil is the existence of free fatty acid as the by product in transesterification process. In this paper we use waste sunflower oil for biodiesel production through single stage trans esterification process. Nov 25, 2019 biodiesel is a diesel fuel that is made by reacting vegetable oil cooking oil with other common chemicals. The procedures that produce biodiesel from waste cooking oil, however, are complicated by free fatty acids that are present as a result of the hydrolysis of the triglyceride under the conditions used for cooking scheme 2. Nov 21, 20 calculation type of oil average volume ml weight of naoh required g wco unfiltered 4. Therefore, the food versus fuel debate can be avoided.

In this regard, waste cooking oil wco 17, 18 and waste animal fat 19,20 waf have been used as feedstock for biodiesel to avoid the use of cultivated land. A recent report international grains council 2008 indicated that rapeseed oil was the predominant feedstock for worldwide biodiesel production in 2007 48%, 4. The first step is to esterify the ffa with methanol by acid catalysis. This undergraduate organic laboratory exercise involves the sulfuric acidcatalyzed conversion of waste vegetable oil into biodiesel. Free fatty acids will increase the time required for heating vegetable oil. Nov 06, 2016 it is prepared from waste vegetable oils and animal fats by transesterification process. Biodiesel synthesis was performed as transesterification of edible and waste cooking sunflower oil catalysed by free lipase from thermomyces lanuginosus lipolase 100l. This process is important to convert free fatty acid ffa in oil to ester. Preparation of biodiesel from waste cooking oil via two.

Extraction of biodiesel from waste vegetable oil clean. Preparation of biodiesel heat 250ml of the oil at 60o c to remove moisture content, by using heating mantle. Waste cooking oil provides a cheaper way of biodiesel production. This has played a pivotal role in lowering the production cost and reducing the demand for other nonrenewable sources of energy. Pdf production of biodiesel from waste cooking oil by. Preparation of waste cooking oil based biodiesel using. Transesterification is the commonly process that used widely compare to other process.

This preparation of biodiesel is very similar to one of the methods used commercially. Preparation, characterization and application of zeolite. Microwaveassisted catalytic transesterification using bao and koh was evaluated for the. The researchers reported earlier on production and characterization of various biodiesel from sunflower oil, coconut oil, palm oil and waste cooking oil through a transesterification process 12. Production of biodiesel from waste cooking oil by transesterification process using potassium hydroxide as catalyst. The acidcatalyzed method, although inherently slower than the basecatalyzed methods, does not suffer from the loss of product or the creation of emulsion producing soap that plagues the basecatalyzed methods when used with waste vegetable oil. Preparation of biodiesel from waste cooking oil essay. The parameters affecting biodiesel production process such as alcohol to oil molar ratio, catalyst concentration, the presence of tetrahydrofuran thf as a cosolvent, and the volumetric flow rates of. Biodiesel is synthesized by direct transesterification. The shell contained caco 3 which was converted to cao after calcination at temperatures 800c for 4 h and cao was acknowledged as an effective heterogeneous catalyst for the transesterification of waste cooking oil.

Jan 16, 2020 the acceleration of the biodiesel glycerol separation has attracted the interest of many researchers in a quest to improve biodiesel production efficiency and reduce the overall production time. Therefore, production of biodiesel from waste cooking oil is the best alternative and further studies need to be done on the characterization of waste cooking oil. Cost of biodiesel produced from virgin vegetable oil through transesterification is higher than that of fossil fuel, because of high raw material cost. Pdf in the present study biodiesel was synthesized from waste cook oil wco by threestep method and regressive analyzes of the process.

The main generators of these residuals they are the industries of fritters, and establishments of preparation of quick food. In this experiment the biodiesel will be made from fresh vegetable oil to avoid the solids and a titration to determine the mass of sodium hydroxide needed to react with the whole oil molecules. Preparation of biodiesel from waste cooking oil and studythe effect on performance of diesel engine. Preparation of biodiesel is carried out on the lab scale. The use of waste cooking oil as biodiesel feedstock reduces the cost of biodiesel production. One of the ways to treat the waste oil is by converting to biodiesel. For trans esterification process we use naoh as catalyst. Transesterification and production of biodiesel from waste. It is alkali catalyzed reaction which involves waste cooking oil, methanol, and potassium hydroxide. Pdf preparation of biodiesel from waste cooking oil via two. Biodiesel production from waste cooking oil using sulfuric. It originates from the preparation of food in the cafeterias and can be harmful to the environment.

Pdf synthesis of biodiesel from waste cooking oil researchgate. Solid acid heterogeneous catalysts have a unique advantage in esterification and transesterification reactions which enhances the use of high acid value oil to be used as feedstock for synthesis of biodiesel. Acidcatalyzed preparation of biodiesel from waste vegetable. In the present study biodiesel was synthesized from waste cook oil wco by threestep method and regressive analyzes of the process was done. Cooking oil is used in substantial quantity for food frying either in home, restaurants or in food industry. Ester content, calculated according with the modified method of en14214, equal to 97. Satputaley assistant professor of mechanical engineering academic year 201011 department of mechanical.

The optimum conditions of biodiesel made from waste cooking oil, effect of reaction time, alcoholoil ratio and catalyst dosage to the biodiesel conversion were explored by using orthogonal experiment design. Technoeconomic evaluation of biodiesel production from. The term waste vegetable oil wvo refers to vegetable oil which has been used in food production and which is no longer viable for its intended use. Moreover, the price of edible plant and vegetable oils is usually higher than petro diesel. For vegetable oil and biodiesel, contaminants must be removed before entering an engine. Synthesis of biodiesel from secondused cooking oil sciencedirect.

Pdf preparation of biodiesel from sunflower oil by. Recent strategy of biodiesel production from waste cooking. Preparation of biodiesel from waste cooking oil essay example. Wco can be converted into biodiesel by transesterification 10,11,12. Recovery of waste cooking oil used in the biodiesel. Under the basic transesterification conditions scheme 3, the free fatty acids become deprotonated.

Optimization of operation conditions for biodiesel. Production of biodiesel from waste vegetable oil via km. Optimization of biodiesel production from waste cooking oil. Reusing of these waste greases can not only reduce the burden of the government in disposing the waste, maintaining public sewers and treating the oily wastewater, but also lower the production cost of biodiesel significantly. Pdf preparation of biodiesel from waste cooking oil via. Waste cooking oil as an alternate feedstock for biodiesel. The production of biodiesel from used cooking oil begins with mixing raw materials of used cooking oil collected into one. Food supply will not be affected by the use of nonedible materials such as wco as feedstock for biodiesel preparation. Synthesis and characterization of biodiesel from waste. These shortcomings are complemented by using waste cooking oil wco, which can substitute vegetable oil. Applications of waste cooking oil other than biodiesel.

Preparation of biodiesel from waste cooking oil and. Conversion of waste cooking oil to biodiesel 11 biodiesel feedstock competes with the use of land for food production. Hence, a combined process with acid catalyzed pretreatment was developed to synthesize biodiesel from waste cooking oil. The acid value is measured for the two types of oil, viscosity and density. Gashaw and others published production of biodiesel from waste cooking oil and factors affecting its formation. Dont use a gas burner for this or any other stage of the biodiesel creation process. A comparative study of biodiesel production from waste cooking oil using sulfuric acid twostep and microwaveassisted transesterification onestep was carried out. In this regard the biodiesel fuel has been demonstrated to be successfully produced from waste. The production of biodiesel from waste vegetable oil offers a triplefacet solution. Transesterification method gives lower yield than threestep method. The type of process that used to produce biodiesel is transesterification. Indias biodiesel processing capacity is estimated at 600,000 tons per year. Pour your used oil into a large, clean cooking pot and heat it to 95.

Additionally, the use of waste fried cooking oil wfco as a reactant for biodiesel plant helps in disposing this waste and reduction of feedstock production. Biodiesel production from waste cooking oil intechopen. Technoeconomic evaluation of biodiesel production from waste. Among the alternatives as a vegetal raw material to extract the oil are. For waste cooking oil, after collection from homes, it is left for 24h to settle any solid residues, and then the oil is preheated at 80oc for 30min.

The random mixer of different oil was used for biodiesel preparation. To determine ffa of sample and biodiesel, 1ml of oil and biodiesel were weighed in gm, then dispersed in 5ml diethylether solution followed by titration against 0. Use a cooking thermometer to monitor the temperature. As crude oil price reach a new high, the need for developing alternate fuels has become acute. Catalysts used in this process are usually acids, base, and lipase. Since lipase catalysts are much expensive, the usage of lipase in biodiesel production is. No modifications are required, and the result is a lessexpensive, renewable, cleanburning fuel. Preparation of biodiesel from waste cooking oil in partial fulfillment of the requirements for the award of the degree of bachelor of engineering in mechanical engineering submitted by ritesh shukla pankaj singh bais ciby ninanankush deshmukh under the guidance of prof. Pdf production of biodiesel from waste cooking oil and. These includes linseed oil, palm seed oil, waste cooked vegetable oil, sunflower seed oil, cotton seed oil, cooking seed oil and animal fats 7, 8, 9.

Biodiesel, transesterification, sunflower oil, waste cooking oil email. As this method becomes increasingly popular, accumulation of waste generated from cooking oil also increases. You can also make biodiesel from waste cooking oil, but that is a little more involved, so lets start with the basics. The optimum conditions of biodiesel made from waste cooking oil, effect of reaction time, alcohol oil ratio and catalyst dosage to the biodiesel conversion were. All reactions are carriedout under atmospheric pressure and 1500 rpm of agitation. The study focus on the physical and chemical properties of waste cooking oil wco, transesterification and production of biodiesel from wco. The biodiesel process used at rit was tailored for the residential cooking oil which tends to be high in water content. Biodiesel from waste cooking oil linkedin slideshare. Injectors, pumps and pistonsseals will be ruined if large particles or the wrong fluids enter them.

Characterization of waste cooking oil for biodiesel production. The acceleration of the biodieselglycerol separation has attracted the interest of many researchers in a quest to improve biodiesel production efficiency and reduce the overall production time. From a waste management standpoint, producing biodiesel from used frying oil is environmentally. Recycling of waste cooking oil for biodiesel production provides economic viability. An improvement in biodiesel production from waste cooking oil by. Along this line, one of the alternative feedstock to produce biodiesel is waste cooking oil wco. Preparation of biodiesel for preparation of biodiesel in the lab alkali catalyzed transesterification is to be used. The diesel engine was developed by rudolf diesel, a french thermal engineer, in 1893 with the. Physicochemical analysis of waste cooking oil reveals the acid value 3. Biodiesel production from waste cooking oil has three solutions those are economic, environmental and waste management 7,8,16,17. The influence factors of biodiesel preparation from waste. One of the effective methods for reducing the cost of biodiesel production is the use of low quality oils which are not suitable for human consumption and readily available such as waste cooking oil wco, animal fat and tall oil 4.

In this work, biodiesel ethyl ester was prepared from waste cooking oil collected from a local restaurant in halifax, nova scotia, canada. The oil used in biodiesel fuel production can be fresh clean oil or used waste oil that has been earlier used for frying as in this study. Waste cooking oil is one of the sources that can contributes to the water pollution. Oil which has been used for cooking will required more of the reactive agents and methanol than fresh oil. Wco was collected from local restaurant of sylhet city in bangladesh.

In fact, our research group have been working in the use of waste cooking oils, to make soap and shampoo how an alternative of waste use in guaranda ecuador 16. Also waste oils and fats used cooking oils are used as a good feedstock, its costs approaches half of the cost of virgin oil4. Heterogeneous catalysts have attracted great attention in recent. Production of biodiesel from waste cooking oil using cao. The production of biodiesel from waste vegetable oils through its pretreatment followed by transesterification process in presence of methanol was investigated using a km micromixer reactor. The waste snail shell was screened to determine its efficiency as heterogeneous catalyst for biodiesel production via transesterification reaction. In a modern society, oil is commonly used for the preparation of food. The project focuses on the production of biodiesel from waste cooking oil which will obtained from restaurants,hotels etc. Dec 12, 2019 biodiesel production from waste cooking oil has three solutions those are economic, environmental and waste management 7,8,16,17.